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The Baylis-Hillman approach to quinoline derivatives
Authors:Familoni Oluwole B  Klaas Phindile J  Lobb Kevin A  Pakade Vusumzi E  Kaye Perry T
Affiliation:Department of Chemistry, Rhodes University, Grahamstown, 6140, South Africa.
Abstract:Baylis-Hillman reactions of 2-nitrobenzaldehydes with various activated alkenes afford adducts that undergo reductive cyclisation to quinoline derivatives. The chemo- and regioselectivity of cyclisation appears to be influenced by the choice of both the substrate and the reagent system, and competing reactions have been observed.
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