Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups |
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| Authors: | Zheng Baishu Bai Junfeng Duan Jingui Wojtas Lukasz Zaworotko Michael J |
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| Affiliation: | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China. |
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| Abstract: | An rht-type metal-organic framework (MOF) prepared from M(2)(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C(3)-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO(2) uptake, an enhanced heat of adsorption, and higher selectivity toward CO(2)/N(2) in comparison with what was previously observed for an analogous MOF with alkyne groups. |
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