Abstract: | Conclusions It was shown that the stereospecificity of SSCC3C,Htrans >3JC,Hcis is applicable as a configurational test for di- and trisubstituted alkenes R2E(Y)C=C(X)H with various heteroatomic substituents (E=N, P, S) and activating groups (X=CO2Alk, CN at Y=H, and X=Y=CO2Alk, CN, CF3).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 779–783, April, 1988. |