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Crystal structures and excimer fluorescence of anisoylbenzoylmethanatoboron and dianisoylmethanatoboron difluorides |
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| Authors: | Mirochnik A. G. Bukvetskii B. V. Fedorenko E. V. Karasev V. E. |
| Affiliation: | (1) Institute of Chemistry of the Far-Eastern Branch of the, Russian Academy of Sciences, 159 prosp. 100 let Vladivostoku, 690022 Vladivostok, Russian Federation |
| Abstract: | The crystal structures and spectral-luminescence properties of anisoylbenzoylmethanatoboron difluoride (1) and dianisoylmethanatoboron difluoride (2) were studied in the solid state and in solution. The structural features of compounds 1 and 2 are responsible for the occurrence of a new type of excimers in solutions, which differs from that observed in the crystalline state. |
| Keywords: | fluorescence crystal structure X-ray diffraction analysis excimer |
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