| 双核配合物[Cu2(TS)(H2O)]·CH3OH的自组装制备和晶体结构 |
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| 引用本文： | 陶偌偈,臧双全,牛景扬,于兆文,周绪亚. 双核配合物[Cu2(TS)(H2O)]·CH3OH的自组装制备和晶体结构[J]. 无机化学学报, 2002, 18(4): 409-412 |
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| 作者姓名： | 陶偌偈 臧双全 牛景扬 于兆文 周绪亚 |
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| 作者单位： | 河南大学化学化工学院,开封,475001 |
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| 基金项目： | 河南省杰出青年基金资助项目，河南省自然科学基金资助项目(No.0040301800，004040300)，河南省教委资助项目(No.99150024)。 |
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| 摘 要： | The binuclear complex [Cu2(TS)(H2O)]·CH3OH, where TS denotes the binucleating ligand derived from the schiff base N,N′-bis(3-carboxylsalidene)trimethylenediamine, was obtained from the self-decomposition of mononuclear complex Na2CuTS·H2O. It crystallizes in the monoclinic system, space group P21/c. The lattice parameters are a=11.935(2)?,b=15.667(3)?,c=11.621(2)?,β=111.60(3)°,V=2020.2(7)?3, Z=4 with R=0.0467. The structure is made of binuclear units, in which two copper atoms are bridged by two phenolic oxygen atoms. The “inside”copper atom is coordinated by two nitrogens, two phenolic oxygens in a planar coordi-nation site, the copper atom deviates from the mean plane by 0.47?. The “outside” copper atom is five coordinated by two phenolic oxygen atoms、two equatorial carboxyl oxygen atoms and one axial water oxygen atom in a distorted tetragonal cone site, the copper atom is pulled out of the equatorial plane by 0.46?.
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| 关 键 词： | 自分解 单斜晶系 变形四方锥 |
| 修稿时间： | 2001-08-31 |
Self-assembly Preparation of Binuclear Complex [Cu2(TS) (H2O)]·CH3OH and its Crystal Structure |
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| TAO Ruo-Jie,ZANG Shuang-Quan,NIU Jing-Yang,YU Zhao-Wen and ZHOU Xu-Ya. Self-assembly Preparation of Binuclear Complex [Cu2(TS) (H2O)]·CH3OH and its Crystal Structure[J]. Chinese Journal of Inorganic Chemistry, 2002, 18(4): 409-412 |
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| Authors: | TAO Ruo-Jie ZANG Shuang-Quan NIU Jing-Yang YU Zhao-Wen ZHOU Xu-Ya |
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| Affiliation: | Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001,Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001,Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001,Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001 and Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001 |
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| Abstract: | |
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| Keywords: | self-decomposition monoclinic system distorted tetragonal cone |
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