Synchronous reactions of free radical formation upon low-temperature chlorination of aromatic and olefinic hydrocarbons |
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| Authors: | S. I. Kuzina S. V. Demidov N. N. Denisov A. I. Mikhailov |
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| Affiliation: | 1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation
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| Abstract: | The free radical formation in reactions of low-temperature (77–150 K) chlorination of monomers and phenols was studied by ESR and calorimetry. The schemes were suggested for multicentered synchronous reactions of radical formation in polymolecular complexes, whose initial composition was directly determined for the first time from the structure of the radicals formed and thermodynamic parameters of the total exothermic effect. |
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