Thermooxidative decomposition of heterocyclic N-oxides |
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Authors: | Yu. A. Gubarev N. Sh. Lebedeva V. P. Andreev Ya. P. Nizhnik A. I. V’yugin |
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Affiliation: | (1) Institute of Solution Chemistry, ul. Akademicheskaya 1, Ivanovo, 153045, Russia;(2) Petrozavodsk State University, Petrozavodsk, Karelia, Russia |
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Abstract: | Thermooxidative decomposition of pyridine N-oxide, 4-(4-dimethylaminostyryl)pyridine N-oxide, 4-(4-methoxystyryl)pyridine N-oxide, quinoline N-oxide, 2-methylquinoline N-oxide, 4-chloroquinoline N-oxide, 2-styrylquinoline N-oxide, and 2-(4-dimethylaminostyryl)quinoline N-oxide was studied. The kinetic parameters of the thermooxidative processes were calculated according to three independent procedures. The relation between the nature of heterocyclic N-oxide and its stability to thermal oxidation was analyzed. |
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