| 电活性聚芳醚酮类环状分子的合成和性质 |
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| 引用本文： | 杨利国,姚雷,王永国,贲腾,张万金. 电活性聚芳醚酮类环状分子的合成和性质[J]. 高等学校化学学报, 2008, 29(3): 655-657 |
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| 作者姓名： | 杨利国 姚雷 王永国 贲腾 张万金 |
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| 作者单位： | 吉林大学麦克德尔米德实验室,长春,130012;吉林大学麦克德尔米德实验室,长春,130012;吉林大学麦克德尔米德实验室,长春,130012;吉林大学麦克德尔米德实验室,长春,130012;吉林大学麦克德尔米德实验室,长春,130012 |
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| 摘 要： | 将电活性苯胺四聚体链段引入聚芳醚酮类刚性大环分子中, 得到了含电活性苯胺链段的聚芳醚酮类大环状分子低聚物C-1, 并通过循环伏安和紫外滴定法证明了这种新型环状分子具有电活性.
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| 关 键 词： | 电活性 环状分子 苯胺链段 聚芳醚酮 |
| 文章编号： | 0251-0790（2008）03-0655-03 |
| 收稿时间： | 2007-12-03 |
| 修稿时间： | 2007-12-03 |
Synthesis and Properties of Poly(aryl ether ketone) Macrocyclic Oligomer with Electroactive Groups |
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| YANG Li-Guo,YAO Lei,WANG Yong-Guo,BEN Teng,ZHANG Wan-Jin. Synthesis and Properties of Poly(aryl ether ketone) Macrocyclic Oligomer with Electroactive Groups[J]. Chemical Research In Chinese Universities, 2008, 29(3): 655-657 |
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| Authors: | YANG Li-Guo YAO Lei WANG Yong-Guo BEN Teng ZHANG Wan-Jin |
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| Affiliation: | Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China |
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| Abstract: | A new electroactive poly(aryl ether ketone) macrocyclic oligmer with phenyl-capped tetramer was synthesized by the modified pseudo-high-dilution method,whose structure with a rigid molecular backbone contains a cavity of well-defined size.The oligomer was characterized with mass spectrometry,IR and 1H NMR,13C NMR spectroscopies.Its redox property was checked by cyclic voltammetry and chemical oxidation process was monitored by UV spectroscopy.We found that it has a reversible electrochemical property like common oligoanilines.Combined with its well-defined structure,the oligmer is expected to act as a kind of host molecules which are capable of molecular recognition. |
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| Keywords: | Electroactivity Macrocyclic oligomer Oligoanilines Poly(aryl ether ketone) |
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