Synthesis and characterization of 1-Methyl-4-mercaptopiperidine complexes of nickel(II), palladium(II) and platinum(II) |
| |
| Authors: | Rosa María Brunet Walter Gaete Pilar González-Duarte Josep Ros |
| |
| Institution: | (1) Departament de Química Inorgànica, Universitat Autònoma de Barcelona, (Bellaterra) Barcelona, Spain |
| |
| Abstract: | Summary Complexes of formulae Ni(HRS)2X2 (X=Cl or Br), M(HRS)2Y2 (M=Ni or Pd; Y=NO2 or C1O4), Pd(HRS)X2 (X=Cl, Br or I), Pt(HRS)X2 (X=Cl or Br), Pt(HRS)2(ClO4)2 and M(RS)2 (M=Pd or Pt) where HRS and RS denote 1-methyl-4-mercaptopiperidine in the zwitterionic or in the thiolato form, respectively, have been prepared and characterized. In all the complexes the ligands are coordinated exclusively through sulphur. Polymeric structures consisting of square-planar geometry with sulphur-bridged metal atoms are proposed in each case. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
