| 钙钛矿太阳能电池中小分子空穴传输材料的研究进展 |
| |
| 引用本文： | 张婧,何有军,闵杰. 钙钛矿太阳能电池中小分子空穴传输材料的研究进展[J]. 物理化学学报, 2018, 34(11): 1221-1238. DOI: 10.3866/PKU.WHXB201803231 |
| |
| 作者姓名： | 张婧 何有军 闵杰 |
| |
| 作者单位： | 1 常州大学材料科学与工程学院，江苏省光伏科学与工程协同创新中心，江苏 常州 2131642 Combiphos Catalyst Inc, Hamilton, NJ 08619, USA3 武汉大学高等研究院，武汉 430072 |
| |
| 基金项目： | the National Natural Science Foundation of China(51603021);the National Natural Science Foundation of China(21702154);the National Natural Science Foundation of China(51773157) |
| |
| 摘 要： | 有机-无机钙钛矿太阳能电池(PSCs)从2009年低于5%的能量转换效率到现在经过认证的超过22%的效率，成为科研热点和最有希望商业化的新型太阳能电池。在高性能的PSCs中，空穴传输材料是关键的一环，起到从钙钛矿活性层材料到对电极有效抽取和传输空穴的作用。本文在现有研究成果的基础上，对有机分子空穴传输材料在PSC中的应用进行总结，并强调分子材料结构对PSC器件性能(效率和稳定性)的影响。
|
| 关 键 词： | 有机分子 分子工程 空穴传输材料 钙钛矿太阳能电池 |
| 收稿时间： | 2018-02-24 |
Recent Progress in Hybrid Perovskite Solar Cells Based on p-Type Small Molecules as Hole Transporting Materials |
| |
| Jing ZHANG,Youjun HE,Jie MIN. Recent Progress in Hybrid Perovskite Solar Cells Based on p-Type Small Molecules as Hole Transporting Materials[J]. Acta Physico-Chimica Sinica, 2018, 34(11): 1221-1238. DOI: 10.3866/PKU.WHXB201803231 |
| |
| Authors: | Jing ZHANG Youjun HE Jie MIN |
| |
| Affiliation: | 1. School of Material Science & Engineering, Jiangsu Collaborative Innovation Center of Photovoltaic Science & Engineering, Changzhou University, Changzhou 213164, Jiangsu Province, P. R. China;2. Combiphos Catalyst Inc, Hamilton, NJ 08619, USA;3. The Insitute for Advanced Studies, Wuhan University, Wuhan 430072, P. R. China |
| |
| Abstract: | Organic-inorganic perovskite solar cells (PSCs) have become one of the most promising solar cells, as the power conversion efficiency (PCE) has increased from less than 5% in 2009 to certified values of over 22%. In the typical PSC device architecture, hole transport materials that can effectively extract and transmit holes from the active layer to the counter electrode (HTMs) are indispensable. The well-known small molecule 2, 2', 7, 7'-tetrakis-(N, N-di-4-methoxy-phenyl amino)-9, 9'-spirobifluorene (spiro-OMeTAD) is the best choice for optimal perovskite device performance. Nevertheless, there is a consensus that spiro-OMeTAD by itself is not stable enough for long-term use in devices due to the sophisticated oxidation process associated with undesired ion migration/interactions. It has been found that spiro-OMeTAD can significantly contribute to the overall cost of materials required for the PSC manufacturing, thus its market price makes its use in large-scale production costly. Besides, another main drawback of spiro-OMeTAD is its poor reproducibility. |
| |
| Keywords: | Organic molecule Molecular engineering Hole transporting material Perovskites solar cells |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
|
点击此处可从《物理化学学报》下载全文 |
|
