Novel oxidative nitrogen to carbon rearrangement found in the conversion of anilines to benzaldoximes by treating with HCHO/H2O2 |
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| Authors: | Naval Kapuriya Narsinh M. Dodia Rajesh Kakadiya Ching-Huang Chen Tsann-Long Su |
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| Affiliation: | a Institute of Biomedical Sciences, Academia Sinica, Taipei 115, Taiwan
b Department of Chemistry, Saurashtra University, Rajkot, India |
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| Abstract: | Novel rearrangement was found by reacting anilines with HCHO/H2O2 resulting in the synthesis of various benzaldoximes. The mechanism of the rearrangement is proposed and suggested that the rearrangement might proceed via unstable N-phenyloxazirane intermediate followed by the transfer of aryl moiety from nitrogen to carbon atom leading to the formation of benzaldoxime. |
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| Keywords: | Rearrangement Amines Oxidation Peroxides Benzaldoximes |
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