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A FACILE APPROAC0H FOR THE SURFACE MODIFICATION OF POLY(VINYLIDENE FLUORIDE)MEMBRANE VIA SURFACE-INITIATED ATOM TRANSFER RADICAL POLYMERIZATION
Authors:Hao Lei  Hai-yin Yu  Ying Lu  Xiao-long Lu  Zhi-kang Xu
Abstract:A novel approach for the surface modification of poly(vinylidene fluoride)(PVDF)membrane was successfully realized through alkaline treatment,UV-induced bromine addition,and followed by surface-initiated atom transfer radical polymerization(ATRP)of methyl methacrylate(MMA).Chemical changes on the PVDF membrane before and after modification were analyzed with attenuated total reflectance Fourier transform infrared spectroscopy(AIR/Fr-IR)and X-ray photoelectron spectroscopy(XPS).Primary kinetic study revealed that the chain growth of poly(methyl methacrylate)(PMMA)from the PVDF surface is consistent with a"controlled"process.
Keywords:Poly(vinylidene fluoride)  Alkaline treatment  Bromine addition  Atom transfer radical polymerization  
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