Conformation of S-vinyl-N,N-diethyldithiocarbamate and C-H...S intramolecular interaction between atoms of olefinic hydrogen and sulfur of thiocarbonyl group according to1H and13C NMR data |
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| Authors: | A V Afonin S V Amosova V I Gostevskaya G M Gavrilova N I Ivanova A V Vashchenko |
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| Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR |
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| Abstract: | According to1H and13C NMR data, in S-vinyl-N,N-diethyldithiocarbamate, which exists primarily in the s-trans conformation with a syn-position of the thiocarbonyl and vinyl groups, a specific interaction C-H...S apparently takes place between the  -hydrogen atoms of the vinyl group and the thiono sulfur.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1978–1982, September, 1990. |
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