Characterization of the redox-reactivity of transition metal oxides by temperature-programmed limited thermal decomposition (TPLTD) |
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Authors: | R Dziembaj J Surman |
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Institution: | (1) Faculty of Chemistry, Jagiellonian University, Karasia 3, PL-30-060 Cracow, Poland |
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Abstract: | The concept of labile lattice oxygen (LLO) as a consequence of the Mars-Van Krevellen model was reminded, and contrasted with the surface oxygen species. Methods of characterizing of the Me-O bond strength were reviewed emphasizing the temperature-programmed limited thermal decomposition (TPLTD). A series of AgxV2MoyOz was characterized by TPLTD. Two forms of LLO were distinguished. The weaker form is independent on Ag-doping, in contrast to the stronger one. Activation energy of TPLTD of the stronger bound LLO was a linear function of the anion vacancy concentration.
Zusammenfassung Aus dem Konzept des labilen Gittersauerstoffs (LLO) als Konsequenz des Mars-Van Krevellen-Modells wird die Rolle der Oberflächen-Sauerstoff-Spezies hervorgehoben. Ein Überblick über die Methoden zur Charakterisierung der Me-O-Bindung wird unter besonderer Betonung der temperaturprogrammierten begrenzten thermischen Zersetzung (TPLTD) gegeben.Eine Reihe Ag
x
V2Mo
y
O2 wurde mittels TPLTD charakterisiert, dabei konnten zwei Arten von LLO unterschieden werden. Die schwächere Form ist im Gegensatz zu der stärkeren unabhängig vom Silbergehalt. Die Aktivierungsenergie der TPLTD der stärker gebundenen LLO hängt linear von der Konzentration der Anionenfehlstellen ab.
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![vcy](/content/t512p28373076526/xxlarge1074.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![bcy](/content/t512p28373076526/xxlarge1073.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![lcy](/content/t512p28373076526/xxlarge1083.gif) ![softcy](/content/t512p28373076526/xxlarge1100.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![fcy](/content/t512p28373076526/xxlarge1092.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![mcy](/content/t512p28373076526/xxlarge1084.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) , ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![zcy](/content/t512p28373076526/xxlarge1079.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![vcy](/content/t512p28373076526/xxlarge1074.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![gcy](/content/t512p28373076526/xxlarge1075.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![vcy](/content/t512p28373076526/xxlarge1074.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![bcy](/content/t512p28373076526/xxlarge1073.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) . ![Ecy](/content/t512p28373076526/xxlarge1069.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![gcy](/content/t512p28373076526/xxlarge1075.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![kcy](/content/t512p28373076526/xxlarge1082.gif) ![tcy](/content/t512p28373076526/xxlarge1090.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![vcy](/content/t512p28373076526/xxlarge1074.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![tscy](/content/t512p28373076526/xxlarge1094.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![tcy](/content/t512p28373076526/xxlarge1090.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![mcy](/content/t512p28373076526/xxlarge1084.gif) ![pcy](/content/t512p28373076526/xxlarge1087.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![tcy](/content/t512p28373076526/xxlarge1090.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![pcy](/content/t512p28373076526/xxlarge1087.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![gcy](/content/t512p28373076526/xxlarge1075.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![mcy](/content/t512p28373076526/xxlarge1084.gif) ![mcy](/content/t512p28373076526/xxlarge1084.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![vcy](/content/t512p28373076526/xxlarge1074.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![gcy](/content/t512p28373076526/xxlarge1075.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![chcy](/content/t512p28373076526/xxlarge1095.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![tcy](/content/t512p28373076526/xxlarge1090.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![mcy](/content/t512p28373076526/xxlarge1084.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![chcy](/content/t512p28373076526/xxlarge1095.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![kcy](/content/t512p28373076526/xxlarge1082.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![dcy](/content/t512p28373076526/xxlarge1076.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![bcy](/content/t512p28373076526/xxlarge1073.gif) ![tscy](/content/t512p28373076526/xxlarge1094.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![bcy](/content/t512p28373076526/xxlarge1073.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![lcy](/content/t512p28373076526/xxlarge1083.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![lcy](/content/t512p28373076526/xxlarge1083.gif) ![softcy](/content/t512p28373076526/xxlarge1100.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![vcy](/content/t512p28373076526/xxlarge1074.gif) ![yacy](/content/t512p28373076526/xxlarge1103.gif) ![zcy](/content/t512p28373076526/xxlarge1079.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![gcy](/content/t512p28373076526/xxlarge1075.gif) ![pcy](/content/t512p28373076526/xxlarge1087.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![dcy](/content/t512p28373076526/xxlarge1076.gif) ![vcy](/content/t512p28373076526/xxlarge1074.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![zhcy](/content/t512p28373076526/xxlarge1078.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![gcy](/content/t512p28373076526/xxlarge1075.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![shcy](/content/t512p28373076526/xxlarge1096.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![tcy](/content/t512p28373076526/xxlarge1090.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![chcy](/content/t512p28373076526/xxlarge1095.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![gcy](/content/t512p28373076526/xxlarge1075.gif) ![kcy](/content/t512p28373076526/xxlarge1082.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![lcy](/content/t512p28373076526/xxlarge1083.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![dcy](/content/t512p28373076526/xxlarge1076.gif) ![yacy](/content/t512p28373076526/xxlarge1103.gif) ![vcy](/content/t512p28373076526/xxlarge1074.gif) ![lcy](/content/t512p28373076526/xxlarge1083.gif) ![yacy](/content/t512p28373076526/xxlarge1103.gif) ![lcy](/content/t512p28373076526/xxlarge1083.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![scy](/content/t512p28373076526/xxlarge1089.gif) ![lcy](/content/t512p28373076526/xxlarge1083.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![jcy](/content/t512p28373076526/xxlarge1081.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![fcy](/content/t512p28373076526/xxlarge1092.gif) ![ucy](/content/t512p28373076526/xxlarge1091.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![kcy](/content/t512p28373076526/xxlarge1082.gif) ![tscy](/content/t512p28373076526/xxlarge1094.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![kcy](/content/t512p28373076526/xxlarge1082.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![tscy](/content/t512p28373076526/xxlarge1094.gif) ![iecy](/content/t512p28373076526/xxlarge1077.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![tcy](/content/t512p28373076526/xxlarge1090.gif) ![rcy](/content/t512p28373076526/xxlarge1088.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![tscy](/content/t512p28373076526/xxlarge1094.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) ![ocy](/content/t512p28373076526/xxlarge1086.gif) ![ncy](/content/t512p28373076526/xxlarge1085.gif) ![ycy](/content/t512p28373076526/xxlarge1099.gif) ![vcy](/content/t512p28373076526/xxlarge1074.gif) ![acy](/content/t512p28373076526/xxlarge1072.gif) ![kcy](/content/t512p28373076526/xxlarge1082.gif) n![scy](/content/t512p28373076526/xxlarge1089.gif) ![icy](/content/t512p28373076526/xxlarge1080.gif) .
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