Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts |
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| Authors: | Lee Hee-Yoon Ryu Suyoung Kang Hongkyu Jun Young-Wook Cheon Jinwoo |
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| Institution: | Center for Molecular Design and Synthesis, Department of Chemistry, KAIST, Daejon, Korea. leehy@kaist.ac.kr |
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| Abstract: | Remarkable selectivity is achieved in the cleavage of benzyl ethers using ball-shaped palladium nanocatalysts, Pd@MCM-48, in an MCM-48 matrix. The unique nanocatalysts not only feature unprecedented complete hydrogenolysis selectivity of a benzyl ether over hydrogenation of a double bond, but also demonstrate selective cleavage of unsubstituted benzyl ether over substituted benzyl ethers. |
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