Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO3) with a rare (10,3)-d net |
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| Authors: | Jinyu Sun Yaming Zhou Guangshan Zhu Rongjing Yang Dongyuan Zhao |
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| Affiliation: | a Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, PR China
b Department of Chemistry, Fudan University, Shanghai 200433, PR China |
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| Abstract: | A basic zinc nitrate, [Zn(OH)(NO3)]n with a novel framework reported herein is prepared by solvothermal synthesis, and holds a rare three-dimensional (10,3)-d net called by Wells. It crystallizes in orthorhombic, space group, Pna21 (No. 33),  ,  ,  , Z=4,  ,  ,  , 3.49<θ<27.51,  , R1=0.029, wR2=0.0773 for 697 (I>2σ(I)) of 1728 [R(int)=0.0246] unique reflections and 59 parameters. GOF=1.073. Interestingly this basic zinc nitrate, [Zn(OH)(NO3)]n behaves well at removal capacity for hydrogen chloride gas, 20.3 g HCl/100 g, and its framework is not destroyed yet. This adsorption character may be useful for the removal of toxic gases in the environment. |
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| Keywords: | Crystal structure Zeotype analogue Zn Polymorphism Adsorption |
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