Three inorganic-organic hybrids of bismuth(III) iodide complexes containing substituted 1,2,4-triazole organic components with charaterizations of diffuse reflectance spectra

The reactions of two kinds of substituted 1,2,4-triazoles with BiI₃ yielded three inorganic-organic hybrids: HL1]₄Bi₆I₂₂]·L1]₄·4H₂O (1) (L1=3-(1,2,4-triazole-4-yl)-1H-1,2,4-triazole); HL2]₄Bi₆I₂₂]·6H₂O (2); HL2]₂Bi₂I₈]·L2]₂ (3) (L2=(m-phenol)-1,2,4-triazole). Both 1 and 2 have polynuclear anions of Bi₆I₂₂]^4- to build up the inorganic layers and substituted 1,2,4-triazoles as the organic layers. Hybrid 3 consists of two BiI₅ square pyramids as inorganic layers. There exist hydrogen bondings and I?I interactions in the structures of 1, 2 and 3. Optical absorption spectra of 1, 2 and 3 reveal the presence of sharp optical gaps of 1.77, 1.77 and 2.07 eV, respectively, suggesting that these materials behave as semiconductors.