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Pressure dependence of the optical-absorption edge of AlN and graphite-type BN
Authors:Hisamitsu Akamaru  Akifumi Onodera  Tadashi EndoOsamu Mishima
Institution:a Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan
b Graduate School of Engineering, Tohoku University, Aoba, Sendai 980-8579, Japan
c National Institute for Research in Inorganic Materials, Tsukuba 305-0044, Japan
Abstract:Effect of pressure on the band gaps on AlN and graphite-type BN (g-BN) has been studied up to 2.7 GPa at room temperature by measuring the optical-absorption edge of single crystals of each substance pressurized in a sapphire-anvil cell. The direct band gap of AlN shifted towards higher energy at a rate of 49±1 meV/GPa, whereas in g-BN the pressure dependence of the band gap was −36±1 meV/GPa. The results are compared with existing first-principles calculations.
Keywords:A  Inorganic compounds  C  High pressure  D  Optical properties
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