| 粉末化学镀负载型NiB/MgO非晶态合金及其加氢催化性能 |
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| 引用本文： | 葛少辉,吴志杰,张明慧,李伟,牟诗诚,陶克毅.粉末化学镀负载型NiB/MgO非晶态合金及其加氢催化性能[J].应用化学,2006,23(3):268-0. |
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| 作者姓名： | 葛少辉 吴志杰 张明慧 李伟 牟诗诚 陶克毅 |
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| 作者单位： | a南开大学化学学院材料化学系；b国家纳米技术产业化基地 |
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| 摘 要： | 粉末化学镀负载型NiB/MgO非晶态合金及其加氢催化性能;NiB/MgO;非晶态合金;粉末化学镀;环丁烯砜加氢
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| 关 键 词： | 粉末化学镀负载型NiB/MgO非晶态合金及其加氢催化性能 NiB/MgO 非晶态合金 粉末化学镀 环丁烯砜加氢 |
| 文章编号： | 1000-0518(2006)03-0268-05 |
| 收稿时间： | 2005-05-24 |
| 修稿时间： | 2005-09-24 |
Preparation of Supported NiB/MgO Amorphous Alloy by Powder Electroless Plating and its Performance in Catalytic Hydrogenation |
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| GE Shao-Hui,WU Zhi-Jie,ZHANG Ming-Hui,LI Wei,MU Shi-Cheng,TAO Ke-Yi.Preparation of Supported NiB/MgO Amorphous Alloy by Powder Electroless Plating and its Performance in Catalytic Hydrogenation[J].Chinese Journal of Applied Chemistry,2006,23(3):268-0. |
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| Authors: | GE Shao-Hui WU Zhi-Jie ZHANG Ming-Hui LI Wei MU Shi-Cheng TAO Ke-Yi |
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| Institution: | a Iustitute of New Catalytic Materiasl Science, College of Chemistry, Nankai University, Tianjin 300071 ; b Nanotechnology Industrialization Base of China, Tianjin |
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| Abstract: | The supported NiB/MgO amorphous alloy catalyst was prepared by powder electroless plating and applied in the catalytic hydrogenation of sulfolene to sulfolane.The XRD,ICP,HRTEM were used to characterize the as-prepared samples,the Ag loading and amount of KBH_(4) in the plating solution were changed to(optimize) the preparation of NiB/MgO catalyst.The characterizations of XRD and SAED revealed the amorphous structure of the sample,and the results of ICP showed that the load of Ag could improve the Ni loading,resulting in enhancing the catalytic activity.Moreover,the different amounts of KBH_(4) in the plating solution could not change the composition of NiB/MgO but has an affect on the load of NiB. |
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| Keywords: | NiB/MgO amorphous alloy electroless plating hydrogenation sulfolene |
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