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Growth of single crystals of monticellite CaMgSiO4: Cr from melt by floating zone technique and the study of their composition
Authors:K. A. Soubbotin  E. V. Zharikov  L. D. Iskhakova  S. V. Lavrishchev
Affiliation:(1) Laser Materials and Technology Research Center, Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 117942, Russia;(2) University of Chemical Technology, Miusskaya pl. 9, Moscow, 125190, Russia;(3) Fiber Optics Research Center, Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 117942, Russia
Abstract:Crystallization of monticellite CaMgSiO4 from melt by the floating-zone technique was studied at different compositions of feed rods. The compositions of rapidly cooled melts and different regions of grown crystals were investigated by the X-ray phase and microprobe analyses. The inclusions of secondary phases were identified. The range of most promising compositions of the charge for technology of growing large high-quality crystals is established. The mathematical model of the changes in the melt composition during monticellite crystallization is constructed.
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