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Low thermal quenching and high-efficiency Ce, Tb-co-doped Ca3Sc2Si3O12 green phosphor for white light-emitting diodes
Authors:Yibo Chen  Kok Wai Cheah
Affiliation:a School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China
b State Key Laboratory of Optoelectronic Materials and Technologies, Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
c Department of Physics, Hong Kong Baptist University, Hong Kong, China
Abstract:Low thermal quenching and high-efficiency Ca3Sc2Si3O12:Ce3+ (CSSO:Ce3+) phosphors with co-doping Tb3+ ion were prepared by a solid state method and the properties of these phosphors were investigated. The results showed that co-doping of Tb3+ not only enhances the photoluminescence remarkably and decreases the thermal quenching of the phosphor, but also heightens the performances of the LEDs fabricated with the phosphor. A high-efficiency and low color temperature white LED was fabricated with the prepared CSSO:1%Ce3+, 0.5%Tb3+ and a red phosphor, indicating that CSSO:1%Ce3+,0.5%Tb3+ phosphor is a suitable green phosphor for the fabrication of high-efficiency white LEDs.
Keywords:LED   Phosphor   Ca3Sc2Si3O12:Ce3+   Co-doping
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