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Electrochemical Synthesis of Polythiophene in an Ionic Liquid
作者姓名:JiaHuaSHI  XunSUN
作者单位:[1]LaboratoryofLubricationandFunctionalMaterials,HenanUniversity,Kaifeng475001 [2]CenterforMolecularSciences,InstituteofChemistry,CAS,Beijing100080
摘    要:Polythiophene(PTh) was prepared by the direct electrochemical synthesis in an ionic liquid (BMIM]PF6) containing 0.1mol/L thiophene by cyclic voltammetry,constant potential and constant current techniques. It is found that smooth and blue-green PTh films can be obtained at a potential of ca. 1.75V(vs. Ag/AgCl) or a current of ca. 1.5mA cm^-2 in the ionic liquid.

关 键 词:电化学合成  离子性液体  聚噻吩

Electrochemical Synthesis of Polythiophene in an Ionic Liquid
Jia Hua SHI,Xun SUN,Chun He YANG,Qing Yu GAO,Yong Fang LI.Electrochemical Synthesis of Polythiophene in an Ionic Liquid[J].Chinese Chemical Letters,2002,13(4):306-307.
Authors:Jia Hua SHI  Xun SUN  Chun He YANG  Qing Yu GAO  Yong Fang LI
Abstract:Polythiophene (PTh) was prepared by the direct electrochemical synthesis in an ionic liquid (BMIM]PF6) containing 0.1 mol/L thiophene by cyclic voltammetry, constant potential and constant current techniques. It is found that smooth and bluegreen PTh films can be obtained at a potential of ca. +1.75 V ( vs. Ag/AgCl ) or a current of ca. 1.5 mA cm-2 in the ionic liquid.
Keywords:Polythiophene  electrochemical synthesis  ionic liquid    
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