Hydrogen exchange between tert-butyl cation and sulfuric acid |
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| Authors: | J. Egyed, Gy. Bujtá s, A. Neszmé lyi J. Tamá s |
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| Affiliation: | (1) Central Research Institute for Chemistry, Hungarian Academy of Sciences, P. O. B. 17, 114 Budapest, Hungary |
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| Abstract: | The D/H exchange between tert-butyl-d9 cation and H2SO4 was investigated. The cation participating in the exchange was recovered in the form of p-di-tert-butylbenzene. The mass spectroscopic measurements show a continuous distribution, from zero to nine, of the deuterium atoms in the tert-butyl group originating from the cation.
             D/H      --d, H2SO4.  ,      ,  --- .    — — - .
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