| 修饰型多相手性催化剂在不对称合成中的应用 |
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| 引用本文： | 李晓东,吕士杰,陈新滋. 修饰型多相手性催化剂在不对称合成中的应用[J]. 化学进展, 2001, 13(1): 33-42 |
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| 作者姓名： | 李晓东 吕士杰 陈新滋 |
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| 作者单位： | 1. 中国科学院兰州化学物理研究所
2. 香港理工大学应用生物与化学科技系 |
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| 基金项目： | 国家自然科学基金资助项目,香港理工大学合作研究课题 |
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| 摘 要： | 本文评述了修饰型多相手性催化剂在不对称合成中的应用。按照不同的制备方法及催化反应对一些多相催化体系进行了归类总结, 包括过渡金属手性配合物的固相化、修饰型手性固体催化剂、手性分子筛及嵌入型粘土手性催化剂。对酒石酸及金鸡纳碱修饰型金属催化剂的反应机理也进行了探讨。
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| 关 键 词： | 不对称合成 多相催化 固相化 手性修饰 手性分子筛 嵌入型粘土手性催化 |
| 文章编号： | 1005-281X(2001)01-0033-10 |
| 收稿时间： | 1999-12-01 |
| 修稿时间： | 1999-12-01 |
The Application of Modified Heterogeneous Chiral Catalysts in Asymmetric Synthesis |
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| Li Xiaodong,Lü Shijie,Chan Albert S C. The Application of Modified Heterogeneous Chiral Catalysts in Asymmetric Synthesis[J]. Progress in Chemistry, 2001, 13(1): 33-42 |
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| Authors: | Li Xiaodong Lü Shijie Chan Albert S C |
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| Affiliation: | State KeyLaboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China Department of Applied Biology and Chemical Technology,HongKong Polytechnic University, HongKong, China" |
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| Abstract: | The application of modified heterogeneous chiral catalysts in asymmetric synthesis is described in this review.Several types of heterogeneous catalytic systems,including immobilized transition metal complexes,chirally modified metal catalysts,chiral zeolite and clay intercalated chiral catalysts,are summarized according to different preparative methods and catalytic reactions.The reaction mechanism in tartrate modified catalysts and cinchona modified catalysts are also discussed. |
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| Keywords: | asymmetric synthesis heterogeneous catalysis immobilization chiral modification chiral zeolite clay intercalated chiral catalysL |
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