Domino Constructions of Pentacyclic Indeno[2,1-c]quinolines and Pyrano[4,3-b]oxepines by [4+1]/[3+2+1]/[5+1] and [4+3] Multiple Cyclizations |
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| Authors: | Bo Jiang Bao-Ming Feng Shu-Liang Wang Shu-Jiang Tu Guigen Li |
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| Institution: | School of Chemistry and Chemical Engineering and Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou 221116, Jiangsu (P.R. China), Fax: (+86)?516-83500065. |
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| Abstract: | New three-component domino reactions have been discovered. The reactions are easy to perform (see scheme; MW=microwave irradiation) and proceed with fast rates, which makes work-up convenient. Most of the multiple stereocenters and the geometry are controlled well. The stereochemistry has been unequivocally determined by X-ray structural analysis. |
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