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Anomalous Melting of Poly(Phenylene Oxide)
Authors:Bair  H E  Kwei  T K
Institution:(1) Bell Laboratories, Lucent Technologies Inc., Murray Hill, NJ 07974, USA;(2) Present address: Polytechnic University, Brooklyn, NY 11201, USA
Abstract:Slow evaporation of toluene from poly(2,6-dimethyl-1,4-phenylene oxide), PPO, at 23°C produced crystals which melt between 185 and 265°C and have a crystallinityof 0.58. About 8 wt% of the crystals appear to melt temperatures below 220°C. The lattertemperature marks the end of the glass transition interval for this polymer.This revised version was published online in November 2005 with corrections to the Cover Date.
Keywords:crystallinity by DSC  enthalpy relaxation  glass transitional interval  heat capacity  melting below Tg  physical aging  PPO crystals
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