用醇羰基化催化剂的合成，表征及溶解性研究

用CuCl，甲醇和空气为原料，合成了甲醇氧化羰基化反应催化剂甲氧基氯化铜，最佳的合成条件是：55度，8h，CuCl与璃的比为1：40（重量比），甲氧基氯化铜的产率为94．5％，对甲氧基氧化铜的溶解进行了讨论；18度时，甲氧基氯化铜在5．3％的氯化氢甲醇溶液中的溶解度为12．3％，用IR，TGA和XRD对所合成的甲氧基氯化铜进行了表征，在IR图谱中发现了官能团－OCH3，CH3的特征吸收峰，证明所合成的产物为甲厮氯化铜，XRD谱显示三个强峰，分别 位于2θ＝11．9度，28．6度，47．5度处，根据TGA知该化合物高于180度时会分解，其失重率为17．5％，与理论值17．7％相当。

SYNTHESIS, CHARACTERIZATION AND SOLUBILITY OF METHANOL CARBONYLATION CATALYST Cu(OCH_3)Cl

Cupric methoxychloride is synthesized by CuCl, CH3 OH and air at ambient condition, and the conversion of CuCl is 94.5% at 55℃, reaction time is 8h and WMeOH: WCuCl = 40: 1. The solubility of cupric methoxychloride is 12.3% at 18℃ in HClCH3OH solution, in which the concentration of HC1 is 5.3%. The cupric methoxychloride was characterized by FTIR, TGA and XRD. IR spectrum show that the bands at 2 936 cm-1 and 2 826 cm-1 could be assigned to the vibration of- OCH3 and - CH3 in the CuOCH3Cl molecule, and the bands at 517cm-1 and 465cm-1 could be assigned to the Cu - O vibration. XRD result show that CuOCH3Cl has three strong bands at 2θ = 11.9°, 28.6° and 47.5° respectively, although CuC1 has the same bands at 28.6° and 47.5°. The product CuOCH3 C1 will decompose above 180℃ with the loss ratio of weight 17.5%, which is quite in agreement with the result of calculation of formula 17.7%.