| 壳聚糖修饰的NiB非晶态合金的制备及表征 |
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| 引用本文： | 武美霞,李伟,张明慧,陶克毅. 壳聚糖修饰的NiB非晶态合金的制备及表征[J]. 物理化学学报, 2011, 27(4): 953-958. DOI: 10.3866/PKU.WHXB20110342 |
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| 作者姓名： | 武美霞 李伟 张明慧 陶克毅 |
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| 作者单位： | 1. Institute of New Catalytic Materials Science, College of Chemistry, Nankai University, Tianjin 300071, P. R. China;2. Department of Chemistry, Shanxi Datong University, Datong 037009, Shanxi Province, P. R. China |
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| 基金项目： | 国家自然科学基金(21073098); 高等教育博士基金(20090031110015); 新世纪优秀人才计划(NCET-10-0481)资助项目~~ |
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| 摘 要： | 以壳聚糖(CS)为稳定剂, 采用化学还原法制备了非负载型NiB非晶态合金催化剂(NiB-CS); 并用 X射线衍射(XRD)、电感耦合等离子体发射光谱(ICP)、X射线光电子能谱(XPS)、透射电镜(TEM)、选区电子衍射(SAED)等表征方法研究了催化剂的非晶性质、原子组成及粒径大小等. 考察了催化剂对糠醇加氢制四氢糠醇反应的催化性能, 并与没有壳聚糖保护的NiB催化剂进行了对比. 结果表明, 加入壳聚糖制得的NiB-CS催化剂的活性组分NiB粒径更小, 表面活性组分浓度更高, 催化活性更高.
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| 关 键 词： | 加氢 壳聚糖 非晶态合金 NiB-CS |
| 收稿时间： | 2010-11-11 |
| 修稿时间： | 2011-02-22 |
Preparation and Characterization of NiB Amorphous Alloy Modified Using Chitosan |
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| WU Mei-Xia,LI Wei,ZHANG Ming-Hui,TAO Ke-Yi. Preparation and Characterization of NiB Amorphous Alloy Modified Using Chitosan[J]. Acta Physico-Chimica Sinica, 2011, 27(4): 953-958. DOI: 10.3866/PKU.WHXB20110342 |
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| Authors: | WU Mei-Xia LI Wei ZHANG Ming-Hui TAO Ke-Yi |
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| Affiliation: | 1. Institute of New Catalytic Materials Science, College of Chemistry, Nankai University, Tianjin 300071, P. R. China;2. Department of Chemistry, Shanxi Datong University, Datong 037009, Shanxi Province, P. R. China |
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| Abstract: | NiB amorphous alloy catalyst (NiB-CS) was prepared by direct reduction using the chemical- reduction method with chitosan as a stabilizer. The amorphous structure, atomic composition, and particle size of the as-prepared catalysts were characterized by X-ray diffraction (XRD), inductively coupled plasma spectrometry (ICP), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and selected area electron diffraction (SAED). The catalytic behavior during the hydrogenation of furfuryl ... |
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| Keywords: | Hydrogenation Chitosan Amorphous alloy NiB-CS |
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