Photolysis of ozone in the ultraviolet region. Reactions of O(1D), O2(1Δg) and O≠2 |
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| Authors: | I Arnold FJ Comes |
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| Institution: | Institut für Physikalische und Theoretische Chemie, Frankfurt am Main, Germany |
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| Abstract: | Reactions of O(1D) and O2(1Δg) with ozone have been observed time resolved by the detection of the product O3P) and their rate constants have been determined. It is found that vibrationally excited molecular oxygen, O≠2, also produces O(3P) in reaction with ozone. These observations are supported by the results of quantum yield determinations of the ozone decomposition in UV-photolysis. |
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