| 桃柱螟性信息素的立体选择性合成 |
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| 引用本文： | 滕有为 孟岳. 桃柱螟性信息素的立体选择性合成[J]. 合成化学, 1993, 1(2): 129-133 |
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| 作者姓名： | 滕有为 孟岳 |
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| 作者单位： | 中国科学院成都有机化学研究所 成都610015 |
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| 摘 要： | 分别以10-十一碳烯酸和丙炔醇为起始原料,通过炔化物路线(第1个中间体是10-十一碳炔醇-1(5),第2个中间体是10-十六碳炔醇-1(8))分别立体选择性合成了桃柱螟性信息素成分(E)-10-十六碳烯醛(1)和(Z)-10-十六碳烯醛(2)。
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| 关 键 词： | 性信息素 立体选择性 合成 |
Synthesis of the Sex Pheromone of the Yellow Peach Moth |
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| Teng You-Wei Meng Yue Wang Jin Feng Liu-Cui Yuan Chen-Guang Wang Shu-Mei Li Yue-Ping Zhu Jin. Synthesis of the Sex Pheromone of the Yellow Peach Moth[J]. Chinese Journal of Synthetic Chemistry, 1993, 1(2): 129-133 |
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| Authors: | Teng You-Wei Meng Yue Wang Jin Feng Liu-Cui Yuan Chen-Guang Wang Shu-Mei Li Yue-Ping Zhu Jin |
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| Abstract: | (E)-10-hexadecenal(1) and(Z)-10-hexadecenal(2)which are compo- nents of the sex pheromone of the yellow peach moth (Dichocrocis punctiferalis Guenee) were stereoselectively synthesized via two acetylenic intermediates(1st is 10-undecynol- 1,2nd is 10-hexadecynol-1)routes using 10-undecenoic acid and proparyl alcohol as starting material,respectively. |
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| Keywords: | Sex pheromone Proparyl alcohol 10-Undecenoic acid 10-Hexadecenal Stereoselectivity |
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