Kinetics of electrochemical nucleation and growth |
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| Institution: | 1. Skoltech Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, 121205 Moscow, Russian Federation;2. Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russian Federation;1. School of Advanced Manufacturing, Department of Chemical Engineering and Advanced Materials, Guangdong University of Technology, Jieyang 522000, China;2. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;3. Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangzhou 510006, China |
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| Abstract: | A united scheme for the kinetics of electrochemical nucleation and the growth of a new phase is presented. The peculiarities of ion-transfer kinetics during electrochemical phase formation are analysed. The influence of the exchange current density at the electrolyte/cluster of the new phase interface on the nucleation rate, the nucleation induction time and the growth rate is reported. |
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