| 多氟芳烃的亲核反应II: 一氯五氟苯的亲核环化 |
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| 引用本文： | 葛文正,胡里清,黄维垣.多氟芳烃的亲核反应II: 一氯五氟苯的亲核环化[J].化学学报,1988,46(11):1109-1112. |
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| 作者姓名： | 葛文正 胡里清 黄维垣 |
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| 作者单位： | 中国科学院上海有机化学研究所 |
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| 摘 要： | 本文报道一氯五氟苯与双官能团亲核试剂反应制备环化产物的研究结果, 发现应用NaH-DMF体系制备醇钠, 有利于亲核反应的顺利进行, 环化产物产率有较大幅度提高.
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| 关 键 词： | 苯P 环化 氟代烃 亲核反应 氯苯P |
The nucleophilic reaction of polyfluoroaromatic compounds II: The nucleophilic cyclization of chloropentafluorobenzene |
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| GE WENZHENG,HU LIQING,HUANG WEIYUAN.The nucleophilic reaction of polyfluoroaromatic compounds II: The nucleophilic cyclization of chloropentafluorobenzene[J].Acta Chimica Sinica,1988,46(11):1109-1112. |
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| Authors: | GE WENZHENG HU LIQING HUANG WEIYUAN |
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| Abstract: | The results of cyclization reaction between chloropentafluorobenzene and bifunctional nucleophiles, such as RCH2CH2OH (R = OH, NHMe, NHEt), HN(CH2CH2OH)2, and NH2CH2CH2NH2, were reported. Thus, stirring C6F5Cl with MeNHCH2CH2OH and NaH in DMF at 60?for 3 h gave cyclization products I and II. |
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| Keywords: | BENZENE P CYCLIZATION FLUOROHYDROCARBON NUCLEOPHILIC REACTION CHLOROBENZENE P |
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