| Synthesis and Crystal Structure of (E)-[1-Ferrocenyl-2-(4-Chlorophenyl) ethylene] |
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| 引用本文： | QIAN Ying, SUN Yue-Ming, LIU Ju-Zheng(Department of Chemistry,Southeast University,Nanjing,210018)CHEN Jian, HU Chun-Hua ,ZHENG Pei-Ju(Research Center of Analysis and Measurement,Fudan University,Shanghai,2OO433). Synthesis and Crystal Structure of (E)-[1-Ferrocenyl-2-(4-Chlorophenyl) ethylene][J]. 结构化学, 1997, 0(4) |
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| 作者姓名： | QIAN Ying SUN Yue-Ming LIU Ju-Zheng(Department of Chemistry Southeast University Nanjing 210018)CHEN Jian HU Chun-Hua ZHENG Pei-Ju(Research Center of Analysis and Measurement Fudan University Shanghai 2OO433) |
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| 作者单位： | QIAN Ying; SUN Yue-Ming; LIU Ju-Zheng(Department of Chemistry，Southeast University，Nanjing，210018)CHEN Jian; HU Chun-Hua ;ZHENG Pei-Ju(Research Center of Analysis and Measurement，Fudan University，Shanghai，2OO433) |
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| 基金项目： | 国家教季博士点基金，江苏省科委基金 |
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| 摘 要： | 1INTRoDUCTIoNCurrently,thereisaconsiderableinterestintheinvestigationoforganicandorganometallicmaterialsshowinglargenonlinearopticalresponse.Theirpotentialusehasbeenresearchedindeviceapplicationswhicharerelatedtothetelecommuni-cations,opticalcomputingandopticalinformationprocessing"2i.Onamicroscopiclevel,oneofthemajorphysicalparameterstodecidethenonlinearopticalpropertiesofmaterialsisthemolecularhyperpolarizability,avaluedeterminedbyelectronicandgeometricstructureofmolecule.Thetitlecompoun…
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Synthesis and Crystal Structure of (E)-[1-Ferrocenyl-2-(4-Chlorophenyl) ethylene] |
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| QIAN Ying, SUN Yue-Ming, LIU Ju-Zheng. Synthesis and Crystal Structure of (E)-[1-Ferrocenyl-2-(4-Chlorophenyl) ethylene][J]. Chinese Journal of Structural Chemistry, 1997, 0(4) |
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| Authors: | QIAN Ying SUN Yue-Ming LIU Ju-Zheng |
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| Abstract: | The single crystal structure of the donor-acceptor ferrocenyl derivativeC18H15ClFe (Mr = 322. 62 ) has been determined, belonging to orthorhombic crystalsystem, space group P212121 with lattice parameters a= 11. 307 (2), b= 8. 471 (2 ), c=15. 427(3) A, V= 1477. 7(9) A3, Z=4, D.= 1. 45 g. cm-3, λ(MoKα) =0. 71073A,μ= 11. 9 cm-1, F(000) = 664. The final R value for 1534 observed [I>3σ(I)] reflec-tions is 0. 060. The configuration of the C =C double bond is trans. The C5H4CH =CHC6H4Cl fragrnent is almost planar. The rings of ferrocene are almost in the eclipsedpositions with each other. |
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| Keywords: | ferrocenyl derivative crystal structure donor-acceptor compound transconfiguration |
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