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Preparation and properties of electron donor acceptor complexes of the compounds having capto-dative substituents
Authors:Akira Sugimoto  Takeshi Kotani  Junko Tsujimoto  Shigeo Yoneda
Abstract:In order to examine the “capto-dative” substitution-effect on the electrical conductivity, five compounds which have capto-dative substituents were prepared. Electron withdrawing (capto) group was nitro- or cyano-substituted phenyl and electron donating (dative) one was 5-methyl-5,10-dihydrophenazinyl moiety. The character of intramolecular electron donor acceptor complex of the five compounds were demonstrated by their uv spectra. Electron donor acceptor complexes of them with tetracyanoquinodimethane were prepared and their electrical resistivities were measured.
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