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A study of the graft copolymerization of methacrylic acid onto starch using the H2O2/Fe++ redox system
Authors:B. V  zquez,I. Go  i,M. Gurruchaga,M. Valero,G. M. Guzm  n
Affiliation:B. Vázquez,I. Goñi,M. Gurruchaga,M. Valero,G. M. Guzmán
Abstract:Graft copolymerization of methacrylic acid (MetAc) onto potato starch using H2O2/Fe++ redox system was investigated. The best conditions of the grafting reaction were determined and several variables were studied: initiator and monomer concentrations, time, and temperature. Percent grafting efficiency, percent grafting, percent grafted monomer conversion, and total conversion were obtained. The optimum graft yield was obtained at 7.3 × 10?3M H2O2 concentration and it was favored by increasing the methacrylic acid concentration and reaction time.
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