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Functionalization of crosslinked poly(4-vinylpyridine) and poly(4-vinylpyridine-co-styrene) with permanganate species: Preparation of poly(4-vinylpyridinium permanganate)s and their use as oxidizing reagents
Authors:K J John  V N Rajasekharan Pillai
Abstract:Crosslinked poly(4-vinylpyridine) and poly(4-vinylpyridine-co-styrene) were functionalized with permanganate group to afford the corresponding poly4-vinyl(pyridinium permanganate)] resin. These resins were found to selectively oxidize alcohols to corresponding carbonyl compounds. These insoluble functionalized polymers possess the desired characteristics of the polymeric reagents, including operational simplicity, filterability, and regenerability. The influence of solvent, duration of reaction, and molar excess of the reagent in these oxidation reactions was investigated to find out the optimum conditions for effective oxidation reactions. The reactions were found to be more facilitated in nonpolar solvents, and a large excess of the polymeric reagent did not have any significant effect on the extent of reactions. The poly4-vinyl(pyridinium permanganate)] resin bears a contrast to KMnO4 and other polymer-supported oxidizing agents like poly4-vinyl(pyridinium chlorochromate)] in that it does not bring about the oxidation of the alcohol group directly attached to the ring structure.
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