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13C-NMR study of cellulose derivatives in the solid state
Authors:M Hoshino  M Takai  K Fukuda  K Imura  J Hayashi
Abstract:The application of NMR for natural organic compounds has been carried out from the early history of NMR. But they reported on the liquid state NMR and the samples were limited to the materials which dissolved in proper solvents. It has been possible to measure the samples in the solid state in 1970s and is widely used as a familiar analytical method in 1980s. Whereas some of the data is inadequate, concerning cellulose derivatives, in particular, only nitrate and acetate were reported by Patterson1 and Doyle,2 respectively. In this paper, the 13C CP/MAS solid state NMR spectra of several cellulose derivatives are shown and the relationship between the structure and spectrum is discussed.
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