A unified quantum theory of mechanics and thermodynamics. Part IIb. Stable equilibrium states |
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Authors: | George N. Hatsopoulos Elias P. Gyftopoulos |
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Affiliation: | (1) Massachusetts Institute of Technology, Cambridge, Massachusetts |
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Abstract: | Part IIb presents some of the most important theorems for stable equilibrium states that can be deduced from the four postulates of the unified theory presented in Part I. It is shown for the first time that the canonical and grand canonical distributions are the only distributions that are stable. Moreover, it is shown that reversible adiabatic processes exist which cannot be described by the dynamical equation of quantum mechanics. A number of conditions are discussed that must be satisfied by the general equation of motion which is yet to be discovered.Part I of this paper appeared inFound. Phys.6(1), 15 (1976). Part IIa appeared inFound. Phys.6(2), 127 (1976). The numbering of the sections, equations, and references in this part of the paper continues from those in Part IIa. |
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