钠分子里德堡能级的无多普勒加宽光光三共振光谱以及能级宽度和谱线位移

首次报道了钠分子一系列里德堡能级的无多普勒加宽光光三共振（ＤＦ－ＯＯＴＲ）激发荧光光谱，测量了其谱线宽度和其谱线位置随温度、外加气体压力的变化情况。结果表明，钠分子里德堡能级（ｎ＝５～８）的自然宽度（含均匀加宽）在６０～１３０ＭＨｚ之间，其大小主要与主量子数ｎ有关。随钠原子浓度增大（温度升高），或外加Ａｒ气压力增大时，钢分子各个里德堡能级谱线均出现红移，数量在１００ＭＨｚ／τ之内，但位移速率大小不一。

The DF-OOTR Spectra of Rydberg Levels in Sodium Molecules and the Widths and Lineshifts of These Energy Levels

This paper reports for the first time the Doppler-free optical-optical tripleresonance(DF-OOTR) excitation fluorescence spectra for a series of Rydberg energy levels in sodium molecules, and the linewidths and lineshifts under the variations of temperature and foreign buffer-gas pressure. The results demonstrated that the natural widths(including homogeneuos broadening) of these Rydberg energy levels (n=5～8)are between 60～130 MHz, and mainly depend on the principal quantum number n. All these levels are in red line-shifts with the increase of atomic density (the increase of temperature) or foreign buffer-gas (Ar) pressure, but with different shift rate within 100 MHz/τ.