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Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers |
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| Authors: | Dr. Jan Lorkowski Dylan Bouetard Patrick Yorkgitis Dr. Milan Gembicky Dr. Thierry Roisnel Dr. Nicolas Vanthuyne Prof. Dr. Dominik Munz Dr. Ludovic Favereau Prof. Dr. Guy Bertrand Dr. Marc Mauduit Dr. Rodolphe Jazzar |
| Affiliation: | 1. UCSD–CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA-92093-0343 USA;2. Univ Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, 35000 Rennes, France;3. Aix Marseille Univ., CNRS, Centrale Marseille, ISM2, 13013 Marseille, France;4. Coordination Chemistry, Saarland University, Campus C4.1, 66123 Saarbrücken, Germany;5. Univ Rennes, CNRS, ISCR - UMR 6226, 35000 Rennes, France |
| Abstract: | Organic circularly polarized luminescence (CPL)-active molecular emitters featuring dynamic propeller-like luminophores were prepared in one step from cyclic(alkyl)(amino) carbenes (CAACs). These molecules exhibit through-space arene-arene π-delocalization and rapid intramolecular inter-system crossing (ISC) in line with their helical character. |
| Keywords: | Carbene Circularly Polarized Luminescence Density Functional Theory Helical Propeller |