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A Polarized Gel Electrolyte for Wide-Temperature Flexible Zinc-Air Batteries |
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| Authors: | Miaolun Jiao Lixin Dai Hong-Rui Ren Mengtian Zhang Xiao Xiao Boran Wang Jinlong Yang Bilu Liu Guangmin Zhou Hui-Ming Cheng |
| Affiliation: | 1. Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055 China;2. Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055 China These authors contributed equally to this work.;3. Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055 China College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060 China These authors contributed equally to this work.;4. College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060 China;5. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016 China |
| Abstract: | The development of flexible zinc-air batteries (FZABs) has attracted broad attention in the field of wearable electronic devices. Gel electrolyte is one of the most important components in FZABs, which is urgent to be optimized to match with Zn anode and adapt to severe climates. In this work, a polarized gel electrolyte of polyacrylamide-sodium citric (PAM-SC) is designed for FZABs, in which the SC molecules contain large amount of polarized −COO− functional groups. The polarized −COO− groups can form an electrical field between gel electrolyte and Zn anode to suppress Zn dendrite growth. Besides, the −COO− groups in PAM-SC can fix H2O molecules, which prevents water from freezing and evaporating. The polarized PAM-SC hydrogel delivers a high ionic conductivity of 324.68 mS cm−1 and water retention of 96.85 % after being exposed for 96 h. FZABs with the PAM-SC gel electrolyte exhibit long cycling life of 700 cycles at −40 °C, showing the application prospect under extreme conditions. |
| Keywords: | Flexible Zinc-Air Batteries High Ionic Conductivity Polarized Gel Electrolyte Wide Operating Temperature Zn Dendrite Free |