Framework Structure of a Synthetic High Silica Zeolite --ZSM-39 from a C_2H_4(OH)_2-H_2O Mixed Solvent System |
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摘 要: | The structural analogy of clathrate synthesized with natural zeolite framework is well known. HPF_6·6H_2O and (CH_3)_4 (OH)·5H_2O are isostructural with sodalite,melanophlogite is isostructural with the 12 cubic gas hydrate and zeolite ZSM-39 with the 17 gas hydrate. The synthesis of ZSM-39 was first reported by Brace in 1981.Schleker and Meier also obtained the crystals of ZSM-39 with size<10μm and analyzed its crystal stucture by the powder X-ray diffraction.In 1984,Gies solved the crystal structure of dodecasil 3C(ZSM-39) synthesized from an aqueous system in space group F_(ds).In the present paper,we report the framework structure of the high silica zeolite—ZSM-39 obtained from the ethylene glycol-water mixed solvent system.
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收稿时间: | 1988-02-26 |
Framework Structure of a Synthetic High Silica Zeolite--ZSM-39 from a C2H4(OH)2-H2O Mixed Solvent System |
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Authors: | Yang Guangdi Feng Shouhua Xu Ruren |
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Institution: | 1. Institute of Theoretical Chemistry, Jilin University, Changchun;
2. Department. of Chemistry, Jilin University, Changchun |
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Abstract: | |
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Keywords: | ZSM-39 X-ray Structure |
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