Cationic polymerization of allyl glycidyl ether in solvents of different basicity |
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| Authors: | T. V. Grinevich P. A. Belyakov A. A. Solov’yanov |
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| Affiliation: | (1) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia;(2) Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia |
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| Abstract: | The boron trifluoride tetrahydrofuranate-catalyzed cationic polymerization of allyl glycidyl ether in carbon tetrachloride proceeds via an oxirane cycle to form initially cyclic products and, at later stages, high-molecular-mass products. In the case of 1,2-dimethoxyethane, the polymerization of allyl glycidyl ether occurs via insertion of the monomer into a dissociated bond of a Lewis acid-dimethoxyethane complex and yields a linear polymer with end methoxy groups. |
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