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The synthesis and physicochemical and catalytic properties of SHS zeolites
Authors:L. M. Velichkina  L. L. Korobitsyna  A. V. Vosmerikov  V. I. Radomskaya
Affiliation:(1) Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, Akademicheskii pr. 3, Tomsk, 634055, Russia;(2) Institute of Geology and Nature Management, Far East Division, Russian Academy of Sciences, Blagoveshchensk, Russia
Abstract:Superhigh-silica ZSM-type zeolites with silica moduli of 100–220 were synthesized using hexamethylenediamine as a structure-forming additive. Physicochemical methods were used to identify them as ZSM-5-type zeolites, determine their degree of crystallinity, specific surface areas, and morphology of crystals, and study the phase and elemental composition. The strength and concentration of acid centers were found to decrease as the silica modulus grew. The zeolites obtained can be used as the main component of catalysts for refining low-octane gasoline fractions and methanol conversion into hydrocarbons.
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