Systematizing structural motifs and nomenclature in 1,n'-disubstituted ferrocene peptides |
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Authors: | Kirin Srećko I Kraatz Heinz-Bernhard Metzler-Nolte Nils |
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Institution: | Institut für Pharmazie und Molekulare Biotechnologie, Universit?t Heidelberg, Im Neuenheimer Feld 364, D-69120 Heidelberg, Germany. |
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Abstract: | Ferrocene peptide conjugates display an array of structural features including helical ferrocene based chirality and a number of different intramolecular hydrogen bonding patterns. In this tutorial review we present a rigorous nomenclature for these systems, followed by a section that summarises and categorises the structures known to date. The issues discussed herein are of general relevance for all metallocene-based chiral transition metal catalysts and peptide turn mimetics. |
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