Platinum(III) formation and stabilization as “platinum blues” with different types of ligands in the course of their interaction with PtCl4
2- and cis-Pt(NH3)2CI2 |
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| Authors: | M Mitewa G Gencheva |
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| Institution: | 1. Department of Chemistry, University of Sofia, 1126, Sofia, Bulgaria
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| Abstract: | Studying the kinetics of PtCl4
2-
cis-Pt(NH3)2(H2O)2]2+ and cis-Pt(NH3)2Cl2 (cis-DDP) reactions with different types of ligands using spectrophotometric, Potentiometric and EPR methods, the conditions for
Pt(III) formation as transient species and its further stabilization as “Platinum Blue” complexes were found. A general method
for obtaining “Platinum Blue” species is suggested. |
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| Keywords: | |
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