| 甲基二氯硅烷缩合反应的研究 |
| |
| 引用本文： | 邱化玉,杜作栋.甲基二氯硅烷缩合反应的研究[J].高等学校化学学报,1989,10(4):423-425. |
| |
| 作者姓名： | 邱化玉 杜作栋 |
| |
| 作者单位： | 山东大学化学系 |
| |
| 摘 要： | 由于聚硅烷具有一些特殊的性质及用途,近年来引起了人们的注意。文献报道的多是主链连有烷基、芳基或芳烷基的聚硅烷,而主链连有活性基团的聚硅烷很少。我们曾合成了主链连有硅氢基团的聚硅烷,并研究了其交联反应。通过硅氢键的反应,可在硅一硅主链上引入一些活性基团,赋予聚硅烷新的特性。本文则报道不同反应条件对甲基二氯硅烷缩合的影响。
|
| 关 键 词： | 甲基二氯硅烷 缩合 聚硅烷 |
| 收稿时间： | 1987-11-14 |
Studies on Condensation Reaction of Methyldiphlorosilane |
| |
| Qiu Huayu,Du Zuodong.Studies on Condensation Reaction of Methyldiphlorosilane[J].Chemical Research In Chinese Universities,1989,10(4):423-425. |
| |
| Authors: | Qiu Huayu Du Zuodong |
| |
| Institution: | Department of Chemistry, Shandong University, Jinan |
| |
| Abstract: | The condensation reaction of methyldichlorosilane in mixed solvents with different proportion of toluene and dioxane via various coupling reagents (Na,K,Li or Na/K alloy) were studied in detail. The effect of reaction temperature and time was also suggested. The structure of polysilane obtained from coupling of MeHSiCl2 by Na/K alloy in THF may be chain-cyclic form. |
| |
| Keywords: | Methyldichlorosilane Condensation Polysilane |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
