Regioselective 1, 2-Addition of Ti(IV)-enolate to α,β-Unsaturated Compounds |
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作者姓名: | GuiShengDENG MingYiLIAO XueTIAN JianBoWANG |
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作者单位: | KeyLaboratoryofBioorganicChemistryandMolecularEngineeringofMinistryofEducation,CollegeofChemistry,PekingUniversity,Beijing100871 |
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摘 要: | The nucleophilic addition of Ti(IV) enolate derived from methyl aryl ketones to α,β-unsaturated compounds was found to be highly selective to give 1, 2 addition products.
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关 键 词: | α β-羰基不饱和化合物 钛烯醇化物 路易斯酸 配向性 碳-碳键 |
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