| A New Reagent for the Reduction of N-Arylsulfonylimines |
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| 引用本文： | CMet Hua ZHANG, Jian Guo SHAO, Shen Yong JIANG, Juan JIANG, Qi ZHONG (Department of Chemistry,Yangzhou University,Yangzhou,225002). A New Reagent for the Reduction of N-Arylsulfonylimines[J]. 中国化学快报, 1998, 0(12) |
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| 作者姓名： | CMet Hua ZHANG Jian Guo SHAO Shen Yong JIANG Juan JIANG Qi ZHONG (Department of Chemistry Yangzhou University Yangzhou 225002) |
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| 作者单位： | Department of Chemistry，Yangzhou University，Yangzhou，225002 |
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| 摘 要： | Potassiumselenatedborohydride(KBHZSe3),sodiumselenatedborohydride(NaBHZSe3)werepreparedfirstbyLalancetteetall.However,sincethen,therehavebeenlittlereportabouttheirapplication.Wehaveusedpotassiumselenatedborohydrideinformamidetoreducearomaticnitrocompounds,andsuccessfullyobtainedthecorrespondinganilines2.Inaddition,wehavealsoreportedthereductionofarylsulfonylchloridestothecorrespondingdisulfidesbysodiumselenatedborohydriderefluxinginCH,CN'.Fromourresearchwork,KBHZSe3andNaBHZSe3werefou…
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A New Reagent for the Reduction of N-Arylsulfonylimines |
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| CMet Hua ZHANG, Jian Guo SHAO, Shen Yong JIANG, Juan JIANG, Qi ZHONG. A New Reagent for the Reduction of N-Arylsulfonylimines[J]. Chinese Chemical Letters, 1998, 0(12) |
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| Authors: | CMet Hua ZHANG Jian Guo SHAO Shen Yong JIANG Juan JIANG Qi ZHONG |
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| Abstract: | N-arylsulfonyimines were reduced easily to the corresponding N-arylsulfonylalnineswith potassium selenated borohydride (KBH2Se3) under reflux in formamide. |
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| Keywords: | N-arylsulfonylimine N-arylsulfonylamine potassium selenated borohydride |
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