Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (mu-eta2:eta2-peroxo)dicopper(II) complex supported by dinucleating ligand |
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| Authors: | Matsumoto Takahiro Furutachi Hideki Kobino Masashi Tomii Masato Nagatomo Shigenori Tosha Takehiko Osako Takao Fujinami Shuhei Itoh Shinobu Kitagawa Teizo Suzuki Masatatsu |
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| Institution: | Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. |
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| Abstract: | A discrete (mu-eta2:eta2-peroxo)Cu(II)2 complex, Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the C=C bond and hydroxylation of THF by H-atom abstraction. |
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